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Earth-abundant IV-VI semiconductor SnSe is regarded as a promising thermoelectric material due to its intrinsic low thermal conductivity. In this report, the highly textured SnSe/Ag2 Se composites were first designed by solid solution method followed by spark plasma sintering(SPS) and their thermoelectric properties in two directions were investigated, and then, the performance of composites was further optimized with an additional ball milling. The coexistence of SnSe and Ag2 Se phases is clearly confirmed by energy-dispersive X-ray spectroscopy(EDX) in transmission electron microscopy(TEM). After ball milling, the size of SnSe grains as well as the incorporated Ag2 Se particles reduces effectively, which synergistically optimizes the electrical and thermal transport properties at high temperature range. As a result, a maximum ZT of ~0.74 at 773 K for SnSe+1.0%Ag_2 Se in the direction vertical to the pressing direction is achieved. Composite engineering with additional ball milling is thus proved to be an efficient way to improve the thermoelectric properties of SnSe, and this strategy could be applicable to other thermoelectric systems. 相似文献
24.
伏彩萍 《有色金属(冶炼部分)》2020,(6):66-69
针对现有柠檬酸铋制备工艺合成时间长、能耗高、产品纯度不高等不足,介绍了一种常温下制备柠檬酸铋的新工艺。新工艺制备时间短,制备的柠檬酸铋产品质量好,合成过程产生的废水可循环利用,废气经碱液循环吸收可生产硝酸钠副产品。 相似文献
25.
Solar photocatalytic hydrogen production from water has been regarded as an ideal way addressing world energy and environmental crises. The technology has long relied on the development of an efficient photocatalyst. In addition to its photocatalytic performance, the large-scale production of certain photocatalyst from the viewpoint of particle application remains a challenge yet has received insufficient focus. Herein, we report an efficient and practical batch preparation system based upon hydrothermal method to the scalable production of chalcogenide nanoparticle photocatalyst. Taking the synthesis of Cd0.5Zn0.5S (CZS) twinned photocatalyst as an example, the outcome of CZS photocatalyst could reach ~0.8 kg in this batched synthesis, which is about 390 times of the lab-scale production in mass amount. It was found that the twinned structure and visible-light absorption property were well maintained. Although further measurements toward the photocatalytic activity indicate slight decrement on solar H2 generation compared to the lab-scale synthesized CZS photocatalyst, a high quantum efficiency of about 40.5% at 425 nm remained. The photocatalytic reaction could also stably proceed for 200 h without notable decay of H2-evolution rate. This work thus provides a powerful means for facile scaling up the chalcogenide nanoparticle photocatalyst at the kilogram level with both high quality and good reproducibility. 相似文献
26.
Ningning Fu Jiaxing Li Ming Wang Lili Ren Youqing Luo 《International journal of molecular sciences》2020,21(22)
An obligate mutualistic relationship exists between the fungus Amylostereum areolatum and woodwasp Sirex noctilio. The fungus digests lignin in the host pine, providing essential nutrients for the growing woodwasp larvae. However, the functional properties of this symbiosis are poorly described. In this study, we identified, cloned, and characterized 14 laccase genes from A. areolatum. These genes encoded proteins of 508 to 529 amino acids and contained three typical copper-oxidase domains, necessary to confer laccase activity. Besides, we performed molecular docking and dynamics simulation of the laccase proteins in complex with lignin compounds (monomers, dimers, trimers, and tetramers). AaLac2, AaLac3, AaLac6, AaLac8, and AaLac10 were found that had low binding energies with all lignin model compounds tested and three of them could maintain stability when binding to these compounds. Among these complexes, amino acid residues ALA, GLN, LEU, PHE, PRO, and SER were commonly present. Our study reveals the molecular basis of A. areolatum laccases interacting with lignin, which is essential for understanding how the fungus provides nutrients to S. noctilio. These findings might also provide guidance for the control of S. noctilio by informing the design of enzyme mutants that could reduce the efficiency of lignin degradation. 相似文献
27.
Tunable Spectrum Selectivity for Multiphoton Absorption with Enhanced Visible Light Trapping in ZnO Nanorods 下载免费PDF全文
Kok Hong Tan Fang Sheng Lim Alfred Zhen Yang Toh Xia‐Xi Zheng Chang Fu Dee Burhanuddin Yeop Majlis Siang‐Piao Chai Wei Sea Chang 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(20)
Observation of visible light trapping in zinc oxide (ZnO) nanorods (NRs) correlated to the optical and photoelectrochemical properties is reported. In this study, ZnO NR diameter and c‐axis length respond primarily at two different regions, UV and visible light, respectively. ZnO NR diameter exhibits UV absorption where large ZnO NR diameter area increases light absorption ability leading to high efficient electron–hole pair separation. On the other hand, ZnO NR c‐axis length has a dominant effect in visible light resulting from a multiphoton absorption mechanism due to light reflection and trapping behavior in the free space between adjacent ZnO NRs. Furthermore, oxygen vacancies and defects in ZnO NRs are associated with the broad visible emission band of different energy levels also highlighting the possibility of the multiphoton absorption mechanism. It is demonstrated that the minimum average of ZnO NR c‐axis length must satisfy the linear regression model of Z p,min = 6.31d to initiate the multiphoton absorption mechanism under visible light. This work indicates the broadening of absorption spectrum from UV to visible light region by incorporating a controllable diameter and c‐axis length on vertically aligned ZnO NRs, which is important in optimizing the design and functionality of electronic devices based on light absorption mechanism. 相似文献
28.
Kai Li Pengfei Fu Daibin Tang Bing Wu Xin Liu 《The International Journal of Advanced Manufacturing Technology》2018,96(5-8):1553-1562
Ti-6Al-4V and Ti-4Al-1.5Mn alloys were employed for electron beam processing with the aim to produce surface textures efficient for fluid-drag reduction. The as-resulted surface textures were examined by using advanced optical microscopy for surface morphology analysis, optical microscopy and scanning electron microscopy for near-surface microstructure observation. The titanium model with electron beam processed surface textures was tested in wind tunnel to evaluate their fluid-drag reduction efficiency. It showed that the as-resulted non-smooth surface was characterized by parallel ridges and grooves, with height and spacing able to be customized by adjusting processing parametres. The ridges displayed continuous scales while the valley of grooves presented V-shaped ripples. Their dimensions were also related to and could be controlled by processing parametres. Further, the near-surface region was occupied by fusion zone, heat-affected zone and base metal from the outermost surface to the underlying bulk alloy. The microstructure of fusion zone was characterized by martensite phase. A heat-affected zone was sandwiched between fusion zone and the underlying base metal, with different microstructural features compared to both fusion zone and the base metal. With respect to fluid-drag reduction efficiency, titanium model with electron beam processed surface textures exhibits a reducing efficiency over 15% at attack angles of 0° and ±1°, with an air flow velocity at 24 m/s. 相似文献
29.
ABSTRACTStudy on dynamic tensile properties and atomic chain fabrication of single nanowire, for understanding its dynamic tensile properties and unique physical properties of atomic chain to fabricate atom scale devices, is one of frontier research issues in nano-scale science. However, how to assemble single nanowire on a tensible micro-structure becomes one of the most difficult problems, which severely restricts the development of this research field. In this paper, after the ultrahigh tensible microelectrode chip is fabricated by micro-electromechanical systems technology, hexamethyldisilazane is utilized to improve hydrophobicity of the chip, and then a micro-droplet dielectrophoresis experimental platform and technology is developed to assemble single nanowire on the sensible microelectrode. Experimental results show that accurate and efficient assembly of single Cu nanowire is realized, which contributes greatly to the further research of dynamic tensile properties and atomic chain fabrication. And for guiding the assembly experiments, finite element technology is also utilized to analyze the local micro electro-field around the microelctrodes during dieletrophoresis experiments. 相似文献
30.